Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides

Myllymäki, Teemu T. T.; Guliyeva, Aynur; Korpi, Antti; Kostiainen, Mauri; Hynninen, Ville; Nonappa, Nonappa; Rannou, Patrice; Ikkala, Olli; Halia, Sami

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Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides

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Title:	Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides
Author(s):	Myllymäki, Teemu T. T. ; Guliyeva, Aynur ; Korpi, Antti ; Kostiainen, Mauri ; Hynninen, Ville ; Nonappa, Nonappa ; Rannou, Patrice ; Ikkala, Olli ; Halia, Sami
Date:	2019
Language:	en
Pages:	4 11739-11742
Department:	Molecular Materials University of Grenoble Biohybrid Materials Department of Bioproducts and Biosystems Department of Applied Physics
Series:	Chemical Communications, Volume 55, issue 78
ISSN:	1359-7345 1364-548X
DOI-number:	10.1039/C9CC04715H
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Citation: Myllymäki , T T T , Guliyeva , A , Korpi , A , Kostiainen , M , Hynninen , V , Nonappa , N , Rannou , P , Ikkala , O & Halia , S 2019 , ' Lyotropic liquid crystals and linear supramolecular polymers of end-functionalized oligosaccharides ' , Chemical Communications , vol. 55 , no. 78 , pp. 11739-11742 . https://doi.org/10.1039/C9CC04715H
Abstract: We synthesized permethylated maltoheptaose oligosaccharides, whose both ends, untrivially, have been functionalized with supramolecular binders 2-ureido-4[1H]-pyrimidinones (UPy) after single ring-opening of β-cyclodextrin counterpart. In 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), they show lyotropic liquid crystallinity. In the dried state they allow linear saccharide-based supramolecular polymers by UPy-dimerization.

Description: \| openaire: EC/H2020/742829/EU//DRIVEN
Permanent link to this item: http://urn.fi/URN:NBN:fi:aalto-202206083621 Email this Export to RefWorks QR Code Print BibTex Tweet