Learning Centre

Hajos-Parrish ketone: approaches toward C-ring prcursors of 7-deoxytaxol

 |  Login

Show simple item record

dc.contributor Aalto-yliopisto fi
dc.contributor Aalto University en
dc.contributor.author Lajunen, M.
dc.contributor.author Koskinen, A.
dc.date.accessioned 2016-09-23T08:16:42Z
dc.date.issued 2000
dc.identifier.citation Lajunen , M & Koskinen , A 2000 , ' Hajos-Parrish ketone: approaches toward C-ring prcursors of 7-deoxytaxol ' , Journal of the Chemical Society, Perkin Transactions 1 , no. 1 , pp. 1439-1443 . https://doi.org/10.1039/a909471g en
dc.identifier.other PURE UUID: 8896995d-4bef-429a-83d7-6388a25cc00d
dc.identifier.other PURE ITEMURL: https://research.aalto.fi/en/publications/8896995d-4bef-429a-83d7-6388a25cc00d
dc.identifier.other PURE FILEURL: https://research.aalto.fi/files/7159156/ms076.PDF
dc.identifier.uri https://aaltodoc.aalto.fi/handle/123456789/22321
dc.description.abstract Two routes were evaluated for the preparation of multiply functionalized cyclohexane derivatives in a stereocontrolled fashion from readily available Hajos–Parrish ketone 1. Reduction (catalytic or dissolving metal) led to the cis-isomer 8, in stark contrast to previous literature. Finally, modification of earlier steroid chemistry allowed the synthesis of the trans-isomer 14. The latter is a useful intermediate for the synthesis of 7-deoxytaxol derivatives. en
dc.format.extent 1439-1443
dc.format.mimetype application/pdf
dc.language.iso en en
dc.relation.ispartofseries Journal Chem. Soc., Perkin Trans. en
dc.relation.ispartofseries issue 1 en
dc.rights openAccess en
dc.title Hajos-Parrish ketone: approaches toward C-ring prcursors of 7-deoxytaxol en
dc.type A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä fi
dc.description.version Peer reviewed en
dc.contributor.department Department of Chemistry en
dc.subject.keyword synthesis
dc.subject.keyword taxol
dc.identifier.urn URN:NBN:fi:aalto-201609234325
dc.identifier.doi 10.1039/a909471g
dc.type.version acceptedVersion

Files in this item

Files Size Format View

There are no open access files associated with this item.

This item appears in the following Collection(s)

Show simple item record

Search archive

Advanced Search

article-iconSubmit a publication