2-Thioanyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterisation of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines

Laitinen, R.H; Heikkinen, V.; Haukka, M.; Koskinen, A.M.P.; Pursiainen, J.

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dc.contributor	Aalto-yliopisto	fi
dc.contributor	Aalto University	en
dc.contributor.author	Laitinen, R.H
dc.contributor.author	Heikkinen, V.
dc.contributor.author	Haukka, M.
dc.contributor.author	Koskinen, A.M.P.
dc.contributor.author	Pursiainen, J.
dc.date.accessioned	2016-09-23T09:21:17Z
dc.date.issued	2000
dc.identifier.citation	Laitinen , R H , Heikkinen , V , Haukka , M , Koskinen , A M P & Pursiainen , J 2000 , ' 2-Thioanyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterisation of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines ' , Journal of Organometallic Chemistry , no. 598 , pp. 235-242 . https://doi.org/10.1016/S0022-328X(99)00711-1	en
dc.identifier.other	PURE UUID: 291c3f41-a49e-4a58-ac00-55f9f37b898a
dc.identifier.other	PURE ITEMURL: https://research.aalto.fi/en/publications/291c3f41-a49e-4a58-ac00-55f9f37b898a
dc.identifier.other	PURE FILEURL: https://research.aalto.fi/files/7157213/2_Thioanisyldichlorophosphine_new_starting_materia.pdf
dc.identifier.uri	https://aaltodoc.aalto.fi/handle/123456789/22405
dc.description.abstract	A new aryldichlorophosphine, 2-thioanisyldichlorophosphine, and its anisyl analogue, 2-anisyldichlorophosphine, were prepared by using an organozinc halide reagent of 2-thioanisole or 2-anisole with ethereal solution of PCl3 in refluxing conditions. From these aryldichlorophosphines, eight new multidentate phosphine ligands containing 2-thioanisyl, 4-thioanisyl, 2-anisyl, 1-naphthyl and 9-anthracenyl groups were synthesized and characterized. Characterization was based mainly on NMR spectroscopy and X-ray crystallography. The crystal structures of six ligands are reported. The electronic effects on basicity of ligands are discussed.	en
dc.format.extent	235-242
dc.format.mimetype	application/pdf
dc.language.iso	en	en
dc.relation.ispartofseries	J. Organomet. Chem.	en
dc.relation.ispartofseries	issue 598	en
dc.rights	openAccess	en
dc.title	2-Thioanyldichlorophosphine, new starting material for the preparation of multidentate phosphine ligands: syntheses and characterisation of derivatives of 2-anisyl- and 2-thioanisyldichlorophosphines	en
dc.type	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä	fi
dc.description.version	Peer reviewed	en
dc.contributor.department	Department of Chemistry	en
dc.subject.keyword	ligands
dc.subject.keyword	phosphine
dc.subject.keyword	synthesis
dc.subject.keyword	thioanyldichlorophosphine
dc.identifier.urn	URN:NBN:fi:aalto-201609234408
dc.identifier.doi	10.1016/S0022-328X(99)00711-1
dc.type.version	acceptedVersion