Fast Aldol-Tishchenko Reactions Utilizing 1,3-Diol Monoalcoholates as the Catalysts

Törmäkangas, Olli P.; Koskinen, Ari M.P.

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dc.contributor	Aalto-yliopisto	fi
dc.contributor	Aalto University	en
dc.contributor.author	Törmäkangas, Olli P.
dc.contributor.author	Koskinen, Ari M.P.
dc.date.accessioned	2016-09-23T09:32:00Z
dc.date.issued	2001
dc.identifier.citation	Törmäkangas , O P & Koskinen , A M P 2001 , ' Fast Aldol-Tishchenko Reactions Utilizing 1,3-Diol Monoalcoholates as the Catalysts ' , ORGANIC PROCESS RESEARCH AND DEVELOPMENT , vol. 5 , no. 4 , pp. 421-425 . https://doi.org/10.1021/op0001335	en
dc.identifier.issn	1083-6160
dc.identifier.other	PURE UUID: fd673a98-6963-4e92-bdeb-8fabd6f025ea
dc.identifier.other	PURE ITEMURL: https://research.aalto.fi/en/publications/fd673a98-6963-4e92-bdeb-8fabd6f025ea
dc.identifier.other	PURE FILEURL: https://research.aalto.fi/files/7159354/ms085.pdf
dc.identifier.uri	https://aaltodoc.aalto.fi/handle/123456789/22492
dc.description.abstract	The aldol-Tishchenko reaction of enolizable aldehydes is a simple and effective way to prepare 1,3-diol monoesters, which are widely used as coalescing agents in the paint industry. The use of monoalcoholates of 1,3-diols as catalysts gives fast and clean reactions compared with the previous use of several inorganic catalysts. The use of the proper 1,3-diol moiety in the catalyst also reduces the amount of side products which are due to ester interchange between product esters and the catalyst. The rapid water-free method developed herein allows fast preparation of monoesters with excellent yield and minimized formation of side products.	en
dc.format.extent	421-425
dc.format.mimetype	application/pdf
dc.language.iso	en	en
dc.relation.ispartofseries	ORGANIC PROCESS RESEARCH AND DEVELOPMENT	en
dc.relation.ispartofseries	Volume 5, issue 4	en
dc.rights	openAccess	en
dc.title	Fast Aldol-Tishchenko Reactions Utilizing 1,3-Diol Monoalcoholates as the Catalysts	en
dc.type	A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä	fi
dc.description.version	Peer reviewed	en
dc.contributor.department	Department of Chemistry	en
dc.subject.keyword	alcoholate
dc.subject.keyword	aldol reaction
dc.subject.keyword	Aldol-Tishchenko reaction
dc.subject.keyword	catalysis
dc.subject.keyword	esterification
dc.subject.keyword	hydride shift
dc.identifier.urn	URN:NBN:fi:aalto-201609234495
dc.identifier.doi	10.1021/op0001335
dc.type.version	acceptedVersion