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Fast Aldol-Tishchenko Reactions Utilizing 1,3-Diol Monoalcoholates as the Catalysts

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dc.contributor Aalto-yliopisto fi
dc.contributor Aalto University en
dc.contributor.author Törmäkangas, Olli P.
dc.contributor.author Koskinen, Ari M.P.
dc.date.accessioned 2016-09-23T09:32:00Z
dc.date.issued 2001
dc.identifier.citation Törmäkangas , O P & Koskinen , A M P 2001 , ' Fast Aldol-Tishchenko Reactions Utilizing 1,3-Diol Monoalcoholates as the Catalysts ' , ORGANIC PROCESS RESEARCH AND DEVELOPMENT , vol. 5 , no. 4 , pp. 421-425 . https://doi.org/10.1021/op0001335 en
dc.identifier.issn 1083-6160
dc.identifier.other PURE UUID: fd673a98-6963-4e92-bdeb-8fabd6f025ea
dc.identifier.other PURE ITEMURL: https://research.aalto.fi/en/publications/fd673a98-6963-4e92-bdeb-8fabd6f025ea
dc.identifier.other PURE FILEURL: https://research.aalto.fi/files/7159354/ms085.pdf
dc.identifier.uri https://aaltodoc.aalto.fi/handle/123456789/22492
dc.description.abstract The aldol-Tishchenko reaction of enolizable aldehydes is a simple and effective way to prepare 1,3-diol monoesters, which are widely used as coalescing agents in the paint industry. The use of monoalcoholates of 1,3-diols as catalysts gives fast and clean reactions compared with the previous use of several inorganic catalysts. The use of the proper 1,3-diol moiety in the catalyst also reduces the amount of side products which are due to ester interchange between product esters and the catalyst. The rapid water-free method developed herein allows fast preparation of monoesters with excellent yield and minimized formation of side products. en
dc.format.extent 421-425
dc.format.mimetype application/pdf
dc.language.iso en en
dc.relation.ispartofseries Volume 5, issue 4 en
dc.rights openAccess en
dc.title Fast Aldol-Tishchenko Reactions Utilizing 1,3-Diol Monoalcoholates as the Catalysts en
dc.type A1 Alkuperäisartikkeli tieteellisessä aikakauslehdessä fi
dc.description.version Peer reviewed en
dc.contributor.department Department of Chemistry en
dc.subject.keyword alcoholate
dc.subject.keyword aldol reaction
dc.subject.keyword Aldol-Tishchenko reaction
dc.subject.keyword catalysis
dc.subject.keyword esterification
dc.subject.keyword hydride shift
dc.identifier.urn URN:NBN:fi:aalto-201609234495
dc.identifier.doi 10.1021/op0001335
dc.type.version acceptedVersion

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